Mid-infrared optical frequency comb spectroscopy using an all-silica antiresonant hollow-core fiber.

We present the first mid-infrared optical frequency comb spectrometer employing an absorption cell based on self-fabricated, all-silica antiresonant hollow-core fiber (ARHCF). The spectrometer is capable of measuring sub-mL sample volumes with 26 m interaction length and noise equivalent absorption sensitivity of 8.3 × 10-8 cm-1 Hz-1/2 per spectral element in the range of 2900 cm-1 to 3100 cm-1. Compared to a commercially available multipass cell, the ARHCF offers a similar interaction length in a 1000 times lower gas sample volume and a 2.8 dB lower transmission loss, resulting in better absorption sensitivity. The broad transmission windows of ARHCFs, in combination with a tunable optical frequency comb, make them ideal for multispecies detection, while the prospect of measuring samples in small volumes makes them a competitive technique to photoacoustic spectroscopy along with the robustness and prospect of coiling the ARHCFs open doors for miniaturization and out-of-laboratory applications.

In-situ background-free Raman probe using double-cladding anti-resonant hollow-core fibers.

This study presents the development of an in-situ background-free Raman fiber probe, employing two customized double-cladding anti-resonant hollow-core fibers (AR-HCFs). The Raman background noise measured in the AR-HCF probe is lower than that of a conventional multi-mode silica fiber by two orders of magnitude. A plug-in device for fiber coupling optics was designed that was compatible with a commercially available confocal Raman microscope, enabling in-situ Raman detection. The numerical aperture (NA) of both AR-HCF claddings exceeds 0.2 substantially enhancing the collection efficiency of Raman signals at the distal end of the fiber probe. The performance of our Raman fiber probe is demonstrated by characterizing samples of acrylonitrile-butadiene-styrene (ABS) plastics, alumina ceramics, and ethylene glycol solution.

Direct performance comparison of antiresonant and Kagome hollow-core fibers in mid-IR wavelength modulation spectroscopy of ethane.

In this paper, we experimentally asses the performance of wavelength modulation spectroscopy-based spectrometers incorporating 1.3 m-long gas absorption cells formed by an antiresonant hollow core fiber (ARHCF) and a Kagome hollow core fiber. To evaluate the discrepancies with minimum methodology error, the sensor setup was designed to test both fibers simultaneously, providing comparable measurement conditions. Ethane (C2H6) with a transition located at 2996.88 cm-1 was chosen as the target gas. The experiments showed, that due to better light guidance properties, the ARHCF-based sensor reached a minimum detection limit of 4 ppbv for 85 s integration time, which is more than two times improvement in comparison to the result obtained with the Kagome fiber.

Low-loss multi-mode anti-resonant hollow-core fibers.

In this work, multi-mode anti-resonant hollow-core fiber (AR-HCF) with 18 fan-shaped resonators is fabricated and characterized. The ratio of core diameter over transmitted wavelengths in the lowest transmission band is up to 85. The measured attenuation at 1 µm wavelength is below 0.1 dB/m and the bend loss below 0.2 dB/m at a bend radius smaller than 8 cm. Modal content of the multi-mode AR-HCF is characterized using the S2 imaging technique and seven LP-like modes in total are identified using a 23.6 meter fiber length. Multi-mode AR-HCFs for longer wavelengths are fabricated by scaling up the same design, extending the transmission window beyond 4 µm wavelength. Low-loss multi-mode AR-HCF could find applications in the delivery of high-power laser light with a medium beam quality, where higher coupling efficiency and laser damage threshold are expected.

Miniature three-photon microscopy maximized for scattered fluorescence collection.

In deep-tissue multiphoton microscopy, diffusion and scattering of fluorescent photons, rather than ballistic emanation from the focal point, have been a confounding factor. Here we report on a 2.17-g miniature three-photon microscope (m3PM) with a configuration that maximizes fluorescence collection when imaging in highly scattering regimes. We demonstrate its capability by imaging calcium activity throughout the entire cortex and dorsal hippocampal CA1, up to 1.2 mm depth, at a safe laser power. It also enables the detection of sensorimotor behavior-correlated activities of layer 6 neurons in the posterior parietal cortex in freely moving mice during single-pellet reaching tasks. Thus, m3PM-empowered imaging allows the study of neural mechanisms in deep cortex and subcortical structures, like the dorsal hippocampus and dorsal striatum, in freely behaving animals.

Two-photon endomicroscopy with microsphere-spliced double-cladding antiresonant fiber for resolution enhancement.

We demonstrate a miniature fiber-optic two two-photon endomicroscopy with microsphere-spliced double-cladding antiresonant fiber for resolution enhancement. An easy-to-operate process for fixing microsphere permanently in an antiresonant fiber core, by arc discharge, is proposed. The flexible fiber-optic probe is integrated with a parameter of 5.8 mm × 49.1 mm (outer diameter × rigid length); the field of view is 210 µm, the resolution is 1.3 µm, and the frame rate is 0.7 fps. The imaging ability is verified using ex-vivo mouse kidney, heart, stomach, tail tendon, and in-vivo brain neural imaging.

Measurements of microjoule-level, few-femtosecond ultraviolet dispersive-wave pulses generated in gas-filled hollow capillary fibers.

To the best of our knowledge, we demonstrate the first time-domain measurement of µJ-level, few-fs ultraviolet dispersive-wave (DW) pulses generated in gas-filled hollow capillary fibers (HCFs) in an atmosphere environment using several chirped mirrors. The pulse temporal profiles, measured using a self-diffraction frequency-resolved optical gating setup, exhibit full width at half maximum pulse widths of 9.6 fs at 384 nm and 9.4 fs at 430 nm, close to the Fourier-transform limits. Moreover, theoretical and experimental studies reveal the strong influences of driving pulse energy and HCF length on temporal width and shape of the measured DW pulses. The ultraviolet pulses obtained in an atmosphere environment with µJ-level pulse energy, few-fs pulse width, and broadband wavelength tunability are ready to be used in many applications.

Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber.

In this paper, the combination of using an anti-resonant hollow-core fiber (ARHCF), working as a gas absorption cell, and an inexpensive, commercially available watch quartz tuning fork (QTF), acting as a detector in the quartz-enhanced photothermal spectroscopy (QEPTS) sensor configuration is demonstrated. The proof-of-concept experiment involved the detection of methane (CH4) at 1651 nm (6057 cm-1). The advantage of the high QTF Q-factor combined with a specially designed low-noise amplifier and additional wavelength modulation spectroscopy with the second harmonic (2f-WMS) method of signal analysis, resulted in achieving a normalized noise-equivalent absorption (NNEA) at the level of 1.34 × 10-10 and 2.04 × 10-11 W cm-1 Hz-1/2 for 1 and 100 s of integration time, respectively. Results obtained in that relatively non-complex sensor setup show great potential for further development of cost-optimized and miniaturized gas detectors, taking advantage of the combination of ARHCF-based absorption cells and QTF-aided spectroscopic signal retrieval methods.

Laser-induced damage of an anti-resonant hollow-core fiber for high-power laser delivery at 1 µm.

We demonstrate high-power laser delivery exceeding 1 kilowatt through a 5-meter homemade anti-resonant hollow-core fiber (AR-HCF) at 1-µm wavelength. Laser-induced damage to the fiber coating and jacket glass is experimentally observed respectively for different incident laser powers from a few hundred watts up to nearly 1.5 kilowatts. The cladding microstructure of the AR-HCF is free of damage at the incident end when 80% of the 1.5-kW incident power is coupled in. The deviation of an incident laser beam from the core to the cladding causes no damage but only deterioration of the coupling efficiency. The potential of the AR-HCF for higher-power laser delivery is discussed.

Fabrication of Microchannels in a Nodeless Antiresonant Hollow-Core Fiber Using Femtosecond Laser Pulses.

In this work, we present femtosecond laser cutting of microchannels in a nodeless antiresonant hollow-core fiber (ARHCF). Due to its ability to guide light in an air core combined with exceptional light-guiding properties, an ARHCF with a relatively non-complex structure has a high application potential for laser-based gas detection. To improve the gas flow into the fiber core, a series of 250 × 30 µm microchannels were reproducibly fabricated in the outer cladding of the ARHCF directly above the gap between the cladding capillaries using a femtosecond laser. The execution time of a single lateral cut for optimal process parameters was 7 min. It has been experimentally shown that the implementation of 25 microchannels introduces low transmission losses of 0.17 dB (<0.01 dB per single microchannel). The flexibility of the process in terms of the length of the performed microchannel was experimentally demonstrated, which confirms the usefulness of the proposed method. Furthermore, the performed experiments have indicated that the maximum bending radius for the ARHCF, with the processed 100 µm long microchannel that did not introduce its breaking, is 15 cm.

Delivery of CW laser power up to 300 watts at 1080†nm by an uncooled low-loss anti-resonant hollow-core fiber.

In this paper, we report the use of a 3-meter low-loss anti-resonant hollow-core fiber (AR-HCF) to deliver up to 300 W continuous-wave laser power at 1080 nm wavelength from a commercial fiber laser source. A near-diffraction-limited beam is measured at the output of the AR-HCF and no damage to the uncooled AR-HCF is observed for several hours of laser delivery operation. The limit of AR-HCF coupling efficiency and laser-induced thermal effects that were observed in our experiment are also discussed.

Antiresonant Hollow-Core Fiber-Based Dual Gas Sensor for Detection of Methane and Carbon Dioxide in the Near- and Mid-Infrared Regions.

In this work, we present for the first time a laser-based dual gas sensor utilizing a silica-based Antiresonant Hollow-Core Fiber (ARHCF) operating in the Near- and Mid-Infrared spectral region. A 1-m-long fiber with an 84-µm diameter air-core was implemented as a low-volume absorption cell in a sensor configuration utilizing the simple and well-known Wavelength Modulation Spectroscopy (WMS) method. The fiber was filled with a mixture of methane (CH4) and carbon dioxide (CO2), and a simultaneous detection of both gases was demonstrated targeting their transitions at 3.334 µm and 1.574 µm, respectively. Due to excellent guidance properties of the fiber and low background noise, the proposed sensor reached a detection limit down to 24 parts-per-billion by volume for CH4 and 144 parts-per-million by volume for CO2. The obtained results confirm the suitability of ARHCF for efficient use in gas sensing applications for over a broad spectral range. Thanks to the demonstrated low loss, such fibers with lengths of over one meter can be used for increasing the laser-gas molecules interaction path, substituting bulk optics-based multipass cells, while delivering required flexibility, compactness, reliability and enhancement in the sensor's sensitivity.

Photoionization-assisted, high-efficiency emission of a dispersive wave in gas-filled hollow-core photonic crystal fibers.

We demonstrate that the phase-matched dispersive wave (DW) emission within the resonance band of a 25-cm-long gas-filled hollow-core photonic crystal fiber (HC-PCF) can be strongly enhanced by the photoionization effect of the pump pulse. In the experiments, we observe that as the pulse energy increases, the pump pulse gradually shifts to shorter wavelengths due to soliton-plasma interactions. When the central wavelength of the blueshifting soliton is close to the resonance band of the HC-PCF, high-efficiency energy transfer from the pump light to the DW in the visible region can be obtained. During this DW emission process, we observe that the spectral center of the DW gradually shifts to longer wavelengths leading to a slightly increased DW bandwidth, which can be well explained as the consequence of phase-matched coupling between the pump pulse and the DW. In particular, at an input pulse energy of 6 µJ, the spectral ratio of the DW at the fiber output is measured to be as high as ∼53%, corresponding to an overall conversion efficiency of ∼19%. These experimental results, well accompanied by theoretical simulations and analysis, offer a practical and effective method of generating high-efficiency tunable visible light sources and provide a few useful insights into the fields of soliton-plasma interaction and resonance-induced DW emission.

Understanding the material loss of anti-resonant hollow-core fibers.

In this paper, the material loss of anti-resonant hollow-core fiber (AR-HCF) and its properties are studied. We revisit the formula of power attenuation coefficient for the index-guiding optical fiber described by Snyder and Love in the 1980s and derive the modal overlap factor that governs the material loss of hollow-core fibers (HCF). The modal overlap factor formula predicts the material loss of AR-HCF, which agrees with numerical simulations by the finite element method. The optimization of silica-based AR-HCF design for the lowest loss at 4 µm wavelength is numerically discussed where the silica absorption reaches over 800 dB/m. Our work would provide practical guidance to develop low-loss AR-HCF at highly absorptive wavelengths, e.g. in the vacuum UV and mid/far-infrared spectral regions.

Highly-tunable, visible ultrashort pulses generation by soliton-plasma interactions in gas-filled single-ring photonic crystal fibers.

Ultrashort laser pulses, featuring remarkable spectral tunability, are highly demanded for nonlinear light-matter interactions in a variety of molecules. Here, we report on the generation of soliton-plasma-driven ultrashort pulses with both bandwidth- and wavelength-tunability in the visible spectral region. Using He-filled single-ring photonic crystal fiber (SR-PCF), we demonstrate in the experiments that the spectral bandwidths of blueshifting solitons can be manipulated by adjusting the input pulse energy, gas pressure and core diameter of the SR-PCF, while the central wavelengths of these solitons can be continuously tuned over 200 nm. We found that in a large-core SR-PCF (24.6-µm core diameter), the bandwidths of blueshifting solitons can be effectively broaden to near 100 nm, pointing out the possibility of generating few-cycle, wavelength-tunable visible pulses using this set-up. In addition, we observed in the experiments that in a small-core SR-PCF (with a core diameter of 17 µm), the blueshifting solitons show little residual light near the pump wavelength, resulting in a high-efficiency frequency up-conversion process. These experimental results, confirmed by numerical simulations, pave the way to a new generation of compact, ultrashort light sources with excellent tunability at visible wavelengths, which may have many applications in the fields of time-resolved spectroscopy and ultrafast nonlinear optics.

Near-infrared long-persistent phosphor of Zn3Ga 2Ge 2O10: Cr³âº sintered in different atmosphere.

A variety of materials sintered in different atmosphere have been well investigated, but there are few reports on the long-persistent phosphorescent materials, especially the near-infrared long-persistent phosphorescent materials sintered in various atmosphere. Changing the surrounding atmosphere is an effective method to improve the afterglow properties of the materials. In this work, we fabricate a typical kind of near-infrared long-persistent phosphorescent materials of Zn3Ga2Ge2O10: 0.5% Cr(3+) in neutral, oxidizing, and reducing atmosphere. By analyzing the XRD patterns, afterglow spectra, decay and thermo-luminescence curves, we discuss the great effects on the structure, long persistent properties and trap properties of the phosphor. This work of obtaining the Zn3Ga2Ge2O10: 0.5% Cr(3+) is of great potential in the applications in night-vision surveillance and in vivo bio-imaging.

Forward scattering light of droplets containing different size inclusions.

Scattering by a sphere with a different internal structure has drawn attention. The forward scattering light of a water droplet containing multiple different size carbon inclusions is calculated by the finite-difference time-domain method. Herein, distribution of these carbon inclusions conforms to Apollonian packing in a droplet. The space left over between carbon inclusions constructs a fractal, of which the fractal dimension D is expressed as D approximately 1.305684. The incident wave is in the y-direction polarization. The results show that the amplitude of the intensity fluctuations is not associated with the fractal dimension. Carbon inclusions only decrease the component y of electric field intensity at the place of inclusions. For a droplet containing multiple concentrated inclusions with different sizes, the amplitude of the intensity fluctuations is related with every space between inclusions. And the far field light intensity approaches the intensity caused by one carbon inclusion as space between inclusions becomes less and less. In order to know the effect of polarization direction, transmissibility versus theta(angle between the polarization direction of the incident wave used and the y-axis direction) is finally obtained. It can be seen that the transmissibility changes with theta conformably and reaches a minimum when theta = 30 degrees. Transmissibility is equal for theta = 90 degrees and theta = 0 degrees.